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6290-49-9 - Methyl methoxyacetate, 99% - Methoxyacetic acid methyl ester - B22528 - Alfa Aesar

B22528 Methyl methoxyacetate, 99%

CAS Number
6290-49-9
Synonyms
Methoxyacetic acid methyl ester

Size Price ($) Quantity Availability
25g 28.20
100g 64.50
500g 246.00
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Methyl methoxyacetate, 99%

MDL
MFCD00008451
EINECS
228-539-9

Chemical Properties

Formula
CH3OCH2CO2CH3
Formula Weight
104.11
Boiling Point
129-130°
Flash Point
35°(95°F)
Density
1.051
Refractive Index
1.3960
Solubility
Soluble in water.

Applications

Methyl methoxyacetate is used in the preparation of 4-hydroxy-2-mercapto-5-methoxypyrimidine (II).

Notes

Keep container tightly closed. Store away from oxidizing agents.

Literature References

Qiuhua Li.; Chuanhui Huang.; Tongwen Xu. Bipolar membrane electrodialysis in an organic medium: Production of methyl methoxyacetate. Journal of Membrane Science. 2009, 339, (1-2), 28-32.

Qiuhua Li.; Chuanhui Huang.; Tongwen Xu. Alcohol splitting for the production of methyl methoxyacetate: Integration of ion-exchange with bipolar membrane electrodialysis. Journal of Membrane Science. 2011, 367, (1-2), 314-318.

The ɑ-lithio-derivative adds to ketones in the normal manner. Elimination of water provides a useful synthesis of ɑ-methoxyacrylates: Tetrahedron Lett., 2825 (1977).

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1742944
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2918.99
TSCA
Yes
RTECS
AI8910000

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