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B22644 1-Iodonaphthalene, 98%

CAS Number
90-14-2
Synonyms

Stock No. Size Price ($) Quantity Availability
B22644-09 10g 62.50
B22644-18 50g 208.00
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1-Iodonaphthalene, 98%

MDL
MFCD00003876
EINECS
201-968-9

Chemical Properties

Formula
C10H7I
Formula Weight
254.07
Melting point
Boiling Point
161-162°/15mm
Flash Point
>110°(230°F)
Density
1.738
Refractive Index
1.7010
Storage & Sensitivity
Light Sensitive.
Solubility
Slightly soluble in water.

Applications

1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.

Notes

Light sensitive. Incompatible with oxidizing agents.

Literature References

G.Kothandaraman; D.W.Pratt; D.S.Tinti. Optically detected magnetic resonance spectra of the lowest triplet state of 1-iodonaphthalene in durene at zero and high magnetic fields. J. Chem. Phys. 1975, 63,(3), 3337.

 

Guillermo A.Lotz; Sara M.Palacios; Roberto A.Rossi. Stereoselective reaction of a chiral assisted amide enolate ion with 1-iodonaphthalene by the SRN1 mechanism. Tetrahedron Letters. 1994, 35,(42), 7711-7714.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1906415
Harmonized Tariff Code
2903.99
TSCA
Yes

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