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600-00-0 - Ethyl 2-bromoisobutyrate, 98+% - 2-Bromoisobutyric acid ethyl ester - Ethyl 2-bromo-2-methylpropionate - B22785 - Alfa Aesar

B22785 Ethyl 2-bromoisobutyrate, 98+%

CAS Number
600-00-0
Synonyms
2-Bromoisobutyric acid ethyl ester
Ethyl 2-bromo-2-methylpropionate

Size Price ($) Quantity Availability
50g 25.24
250g 66.95
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Ethyl 2-bromoisobutyrate, 98+%

MDL
MFCD00000123
EINECS
209-980-6

Chemical Properties

Formula
C6H11BrO2
Formula Weight
195.06
Boiling Point
162-164°
Flash Point
57°(135°F)
Density
1.329
Refractive Index
1.4440
Solubility
Soluble in alcohol, ether. Insoluble in water.

Applications

Ethyl 2-bromoisobutyrate is used as an Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with an ethyl end group.

Notes

Store in cool, dry conditions in a sealed container. Incompatible with oxidizing agents, acids, bases, reducing agents.

Literature References

Maw-ling Wang & Ging-Kun Lam. Hydrolysis Of Ethyl-2-Bromoisobutyrate Ester In An Alkaline Solution. Chemical Engineering Communications. 2004, 191 (2), 220-240.

Hung-Ming Yang; Ch'un-Min Wu and Huai-En Wu. Kinetics for phenolysis of ethyl 2-bromoisobutyrate via phase-transfer catalysis in a solid-liquid system. Journal of Chemical Technology and Biotechnology. 2000, 75 (5), 387-393.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H226

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1098947
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2915.90
TSCA
Yes

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