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Ethyl 2-bromoisobutyrate is used as an Atom Transfer Radical Polymerization (ATRP) initiator that will generate a polymer with an ethyl end group.
Maw-ling Wang & Ging-Kun Lam. Hydrolysis Of Ethyl-2-Bromoisobutyrate Ester In An Alkaline Solution. Chemical Engineering Communications. 2004, 191 (2), 220-240.
Hung-Ming Yang; Ch'un-Min Wu and Huai-En Wu. Kinetics for phenolysis of ethyl 2-bromoisobutyrate via phase-transfer catalysis in a solid-liquid system. Journal of Chemical Technology and Biotechnology. 2000, 75 (5), 387-393.
Hazard Statements: H226-H317-H318-H340
Flammable liquid and vapour. May cause an allergic skin reaction. Causes serious eye damage. May cause genetic defects.
Precautionary Statements: P201-P202-P210-P233-P240-P241-P242-P243-P261-P272-P280g-P281-P303+P361+P353-P305+P351+P338-P308+P313-P310-P333+P313-P363-P370+P378q-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. If skin irritation or rash occurs: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant