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93-99-2 - Phenyl benzoate, 99% - Benzoic acid phenyl ester - B22986 - Alfa Aesar

B22986 Phenyl benzoate, 99%

CAS Number
93-99-2
Synonyms
Benzoic acid phenyl ester

Size Price ($) Quantity Availability
25g 16.80
100g 37.50
500g 124.00
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Phenyl benzoate, 99%

MDL
MFCD00003072
EINECS
202-293-2

Chemical Properties

Formula
C13H10O2
Formula Weight
198.22
Melting point
68-70°
Boiling Point
298-299°
Solubility
Soluble in ethanol, ethyl ether and chloroform. Insoluble in water.

Applications

Phenyl benzoate was used in the synthesis of soluble polyimides using dianhydride/diamine derivatives. It undergoes Fries rearrangement catalyzed by heteropoly acids to yield the acylated phenols and esters. Phenyl benzoate is considered an excellent starting material for the production of optical components, particularly high quality lenses for still and motion picture cameras.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

J. M. Adams and S. E. Morsi. The crystal structure of phenyl benzoate. Acta Cryst. 1997, B32, 1345-1347.

Elena F. Kozhevnikova; Juliette Quartararo; Ivan V. Kozhevnikov. Fries rearrangement of aryl esters catalysed by heteropoly acid. Applied Catalysis A: General. 2003, 245 1, 69-78.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H317

Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction.

Precautionary Statements: P261-P280-P264-P362-P301+P312-P363-P321-P332+P313-P333+P313-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If skin irritation or rash occurs: Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,7275
Harmonized Tariff Code
2916.31
TSCA
Yes
RTECS
DH6299500

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