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Phenyl benzoate was used in the synthesis of soluble polyimides using dianhydride/diamine derivatives. It undergoes Fries rearrangement catalyzed by heteropoly acids to yield the acylated phenols and esters. Phenyl benzoate is considered an excellent starting material for the production of optical components, particularly high quality lenses for still and motion picture cameras.
J. M. Adams and S. E. Morsi. The crystal structure of phenyl benzoate. Acta Cryst. 1997, B32, 1345-1347.
Elena F. Kozhevnikova; Juliette Quartararo; Ivan V. Kozhevnikov. Fries rearrangement of aryl esters catalysed by heteropoly acid. Applied Catalysis A: General. 2003, 245 1, 69-78.
Hazard Statements: H302-H315-H319
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362-P501c
Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant