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B22986 Phenyl benzoate, 99%

CAS Number
93-99-2
Synonyms
Benzoic acid phenyl ester

Stock No. Size Price ($) Quantity Availability
B22986-14 25g 17.10
B22986-22 100g 37.10
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Phenyl benzoate, 99%

MDL
MFCD00003072
EINECS
202-293-2

Chemical Properties

Formula
C13H10O2
Formula Weight
198.22
Melting point
68-70°
Boiling Point
298-299°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ethanol, ethyl ether and chloroform. Insoluble in water.

Applications

Phenyl benzoate was used in the synthesis of soluble polyimides using dianhydride/diamine derivatives. It undergoes Fries rearrangement catalyzed by heteropoly acids to yield the acylated phenols and esters. Phenyl benzoate is considered an excellent starting material for the production of optical components, particularly high quality lenses for still and motion picture cameras.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

J. M. Adams and S. E. Morsi. The crystal structure of phenyl benzoate. Acta Cryst. 1997, B32, 1345-1347.

Elena F. Kozhevnikova; Juliette Quartararo; Ivan V. Kozhevnikov. Fries rearrangement of aryl esters catalysed by heteropoly acid. Applied Catalysis A: General. 2003, 245 1, 69-78.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7275
Harmonized Tariff Code
2916.31
TSCA
Yes
RTECS
DH6299500

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