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1,2-Benzenedimethanol is a raw material used in chemical synthesis.
Quan-Jing Zhu; Wei-Lin Dai; and Kang-Nian Fan. A green process for the oxidative lactonization of 1,2-benzenedimethanol by tungstic acid with aqueous H2O2. Green Chem. 2010, 12 (2), 205-208.
Quanjing Zhu; Xiaofeng Chu; Zhaoyan Zhang; Wei-Lin Dai; Kangnian Fan. Effect of the tungsten precursor on the high activity of the WO3/ZrO2 catalyst in the oxidative lactonization of 1,2-benzenedimethanol. Applied Catalysis A: General. 2012, 435-436, 141-147.
The 7-membered cyclic orthoformates, formed with triethyl or trimethyl orthoformate, are superior reagents for the protection of carbonyl groups as their 2,4-benzodioxepine derivatives. These can be readily cleaved in high yield by Pd-catalyzed hydrogenolysis: Tetrahedron Lett., 30, 4165 (1989); J. Am. Chem. Soc., 116, 558 (1994).
Has also been employed for the protection of boronic acids, by reaction in THF in the presence of a dehydrating agent, e.g. Na2SO4. These derivatives can be readily cleaved by hydrogenolysis or hydrolysis: Tetrahedron Lett., 37, 6705 (1996).
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