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1,2-Dianilinoethane can forms crystalline imidazolidines with aldehydes in the presence of AcOH. N-donating ligand. Can be used as a trapping agent for aldehydes.
G G Schwartz; L W Whitlatch; T C Chen; B L Lokeshwar and M F Holick. Human prostate cells synthesize 1,25-dihydroxyvitamin D3 from 25-hydroxyvitamin D3. Cancer Epidemiol Biomarkers Prev. 1998, 7, 391.
Hartmut Zehender; Dorothea Trescher; Johannes Ullrich. Activity stain for pyruvate decarboxylase in polyacrylamide gels. Analytical Biochemistry. 1983, 135 (1), 16-21.
Forms crystalline imidazolidines with aldehydes in the presence of AcOH; ketones are unreactive: Chem. Ber., 86, 1463 (1953). Can be used as a trapping agent for aldehydes where further reaction could occur: Chem. Ber., 92, 530 (1959); the free aldehyde can be released by acid hydrolysis. Imidazolidine formation can also be catalyzed by 2,3-Dichloro-5,6-dicyanobenzoquinone, A11879: Tetrahedron, 51, 5813 (1995). See also N,N'-Dimethylethylenediamine, L02204.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.