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1,4-dicyanobenzene as a new internal standard in utilizing solid-state infrared intensity methods for the determination of thiocyanate bonding. Used as photosensitizer in [2+2] cycloadditions, nitrile building block.
William C. Fultz; John L. Burmeister; J. Jeffrey MacDougall; John H. Nelson. Evaluation of 1,4-dicyanobenzene as a new internal standard in utilizing solid-state infrared intensity methods for the determination of thiocyanate bonding modes. Inorg. Chem. 1980, 19 (4), 1085-1087.
William P. Heilman; Robert D. Battershell; William J. Pyne; Paul H. Goble; Thomas A. Magee; Richard J. Matthews. Synthesis and antiinflammatory evaluation of substituted isophthalonitriles and trimesonitriles, benzonitriles, and terephthalonitriles. J. Med. Chem. 1978, 21 (9), 906-913.
Photosensitizer in [2+2] cycloadditions: J. Am. Chem. Soc., 110, 8111 (1988), oxidative ring-opening of cyclopropyl compounds: J. Am. Chem. Soc., 119, 10241 (1997), alkoxymethylation reactions by photoinduced cleavage of alkyl trimethylsilymethyl ethers: Angew. Chem. Int. Ed., 37, 660 (1998).
Hazard Statements: H315-H319-H500
Causes skin irritation. Causes serious eye irritation. May form combustible dust concentrations in air
Precautionary Statements: P264b-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362
Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse.