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617-33-4 - Ethyl dibromoacetate, 96% - Dibromoacetic acid ethyl ester - B23209 - Alfa Aesar

B23209 Ethyl dibromoacetate, 96%

CAS Number
617-33-4
Synonyms
Dibromoacetic acid ethyl ester

Size Price ($) Quantity Availability
5g 31.93
25g 82.71
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Ethyl dibromoacetate, 96%

MDL
MFCD00041718
EINECS
210-510-7

Chemical Properties

Formula
C4H6Br2O2
Formula Weight
245.90
Boiling Point
76-78°/12mm
Density
1.902
Refractive Index
1.4990
Solubility
Soluble in hexane, ether, CH2Cl2, acetone, EtOAc, ethanol.

Applications

Ethyl dibromoacetate can be used to produce diphenoxy-acetic acid ethyl ester. It is used in organic synthesis.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

José M. Concellón; Carmen Concellón and Pamela Diaz. An Efficient Synthesis of 2-Bromo-3-hydroxy Esters by Reaction of Ketones with Ethyl Dibromoacetate Promoted by Samarium Diiodide. European Journal of Organic Chemistry. 2006, 2006 (9), 2197-2200.

José M. Concellón and Carmen Méjica. Highly Selective Synthesis of Enantiopure (S,E)-α,β-Unsaturated γ-Amino Esters Through a Sequential Reaction of Ethyl Dibromoacetate with α-Amino Aldehydes Promoted by Chromium Dichloride. European Journal of Organic Chemistry. 2007, 2007 (31), 5250-5255.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2915.90
TSCA
Yes

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