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B23209 Ethyl dibromoacetate, 96%

CAS Number
617-33-4
Synonyms
Dibromoacetic acid ethyl ester

Stock No. Size Price ($) Quantity Availability
B23209-06 5g 32.90
B23209-14 25g 85.20
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Ethyl dibromoacetate, 96%

MDL
MFCD00041718
EINECS
210-510-7

Chemical Properties

Formula
C4H6Br2O2
Formula Weight
245.90
Boiling Point
76-78°/12mm
Density
1.902
Refractive Index
1.4990
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in hexane, ether, CH2Cl2, acetone, EtOAc, ethanol.

Applications

Ethyl dibromoacetate can be used to produce diphenoxy-acetic acid ethyl ester. It is used in organic synthesis.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

José M. Concellón; Carmen Concellón and Pamela Diaz. An Efficient Synthesis of 2-Bromo-3-hydroxy Esters by Reaction of Ketones with Ethyl Dibromoacetate Promoted by Samarium Diiodide. European Journal of Organic Chemistry. 2006, 2006 (9), 2197-2200.

José M. Concellón and Carmen Méjica. Highly Selective Synthesis of Enantiopure (S,E)-α,β-Unsaturated γ-Amino Esters Through a Sequential Reaction of Ethyl Dibromoacetate with α-Amino Aldehydes Promoted by Chromium Dichloride. European Journal of Organic Chemistry. 2007, 2007 (31), 5250-5255.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2915.90
TSCA
Yes

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