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B23452 1-Formylpiperidine, 99%

CAS Number
2591-86-8
Synonyms
Piperidine-1-carboxaldehyde

Stock No. Size Price ($) Quantity Availability
B23452-18 50g 38.00
B23452-30 250g 103.00
B23452-0B 1000g 263.00
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1-Formylpiperidine, 99%

MDL
MFCD00006483
EINECS
219-986-0

Chemical Properties

Formula
C6H11NO
Formula Weight
113.16
Melting point
-31°
Boiling Point
222°
Flash Point
102°(215°F)
Density
1.019
Refractive Index
1.4840
Storage & Sensitivity
Ambient temperatures.
Solubility
Freely soluble in water.

Applications

1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.

Notes

Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

Mary Jo Garber; Martha Gill; Yousheng Hua; Dennis Jenke. Development and Characterization of an LC-MS Method for Quantitating Aqueous Extractables, including Bisphenol A, 1 -Formylpiperidine, and Bis-(pentamethylene)-urea, from Plastic Materials. Journal of Chromatographic Science.2011, 49, (3), 214-220.

Reaction with Grignard or alkyllithium reagents gives aldehydes in high yield: Angew. Chem. Int. Ed., 20, 878 (1981); Org. Synth. Coll., 7, 451 (1990).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H311-H315-H319-H335

Combustible liquid. Harmful if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P361-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
107697
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
TN0380000

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