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B23466 Acenaphthenequinone, 95%

CAS Number
82-86-0
Synonyms

Stock No. Size Price ($) Quantity Availability
B23466-06 5g 22.80
B23466-14 25g 49.30
B23466-22 100g 150.00
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Acenaphthenequinone, 95%

MDL
MFCD00003805
EINECS
201-441-3

Chemical Properties

Formula
C12H6O2
Formula Weight
182.18
Melting point
253-262°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in chloroform and alcohol. Insoluble in water.

Applications

Acenaphthenequinone is used in the preparation of acetylcholinesterase inhibitory agents. It is also used in the preparation of turn-on sensors for cysteine/homocysteine and its application in bioimaging. Further, it is used as an intermediate in manufacturing of dyes and pharmaceuticals. In addition to this, it is used in chemical research as a drug and therapeutic agent.

Notes

Incompatible with strong oxidizing agents.

Literature References

Starting material for a three-step synthesis of corannulene: J. Am. Chem. Soc., 119, 10963 (1997), and also of a new C32H12 bowl-shaped aromatic hydrocarbon: Tetrahedron Lett., 38, 741 (1997).

Lin, Y.; Fu, Z.; Shen, T.; Che, F.; Song, Q. Efficient Protocol for the Synthesis of Novel Spiro[acenaphthylene-1,2'-pyrrolidin]-2-one Compounds. Synth. Commun. 2015, 45 (19), 2188-2194.

Batanero, B.; Ramirez-Moreno, M.; Barba, F. Electroinduced Carbene Formation in the Cathodic Reduction of 1,2-Dicarbonyl Compounds via Electron-Transfer to the Solvent. Electrochim. Acta 2015, 167, 207-212.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
879172
Harmonized Tariff Code
2914.69
TSCA
Yes
RTECS
AB1024500

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