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82-86-0 - Acenaphthenequinone, 95% - B23466 - Alfa Aesar

B23466 Acenaphthenequinone, 95%

CAS Number
82-86-0
Synonyms

Size Price ($) Quantity Availability
5g 18.32
25g 48.41
100g 149.35
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Acenaphthenequinone, 95%

MDL
MFCD00003805
EINECS
201-441-3

Chemical Properties

Formula
C12H6O2
Formula Weight
182.18
Melting point
253-262°
Solubility
Soluble in chloroform and alcohol. Insoluble in water.

Applications

Acenaphthenequinone is used in the preparation of acetylcholinesterase inhibitory agents. It is also used in the preparation of turn-on sensors for cysteine/homocysteine and its application in bioimaging. Further, it is used as an intermediate in manufacturing of dyes and pharmaceuticals. In addition to this, it is used in chemical research as a drug and therapeutic agent.

Notes

Incompatible with strong oxidizing agents.

Literature References

Starting material for a three-step synthesis of corannulene: J. Am. Chem. Soc., 119, 10963 (1997), and also of a new C32H12 bowl-shaped aromatic hydrocarbon: Tetrahedron Lett., 38, 741 (1997).

Lin, Y.; Fu, Z.; Shen, T.; Che, F.; Song, Q. Efficient Protocol for the Synthesis of Novel Spiro[acenaphthylene-1,2'-pyrrolidin]-2-one Compounds. Synth. Commun. 2015, 45 (19), 2188-2194.

Batanero, B.; Ramirez-Moreno, M.; Barba, F. Electroinduced Carbene Formation in the Cathodic Reduction of 1,2-Dicarbonyl Compounds via Electron-Transfer to the Solvent. Electrochim. Acta 2015, 167, 207-212.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
879172
Harmonized Tariff Code
2914.69
TSCA
Yes
RTECS
AB1024500

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