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544-13-8 - Glutaronitrile, 99% - 1,3-Dicyanopropane - Pentanedinitrile - B23663 - Alfa Aesar

B23663 Glutaronitrile, 99%

CAS Number
544-13-8
Synonyms
1,3-Dicyanopropane
Pentanedinitrile

Size Price ($) Quantity Availability
10g 31.60
50g 90.20
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Glutaronitrile, 99%

MDL
MFCD00001970
EINECS
208-861-6

Chemical Properties

Formula
C5H6N2
Formula Weight
94.12
Melting point
-29°
Boiling Point
286-288°
Flash Point
112°(234°F)
Density
0.990
Refractive Index
1.4350
Sensitivity
Hygroscopic
Solubility
Soluble in water, alcohol and chloroform.

Applications

It can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide. It is also used in the preparation of dicarbonyl compounds.

Notes

Hygroscopic. Protect from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Yaser Abu-Lebdeh, et al. New electrolytes based on glutaronitrile for high energy/power Li-ion batteries.J. Power Sources.,2009,189(1), 576-579.

Jae-Young Lee, et al. Characteristics of the DGEBA/MDA system modified with glutaronitrile.Mater. Chem. Phys.,1996,44(1), 74-78.

Can be used for the conversion, by exchange, of carboxylic acids to nitriles, by heating in the presence of phosphoric acid. The equilibrium is displaced by cyclization to glutarimide: J. Org. Chem., 36, 3050 (1971).

GHS Hazard and Precautionary Statements

Hazard Statements: H302

Harmful if swallowed.

Precautionary Statements: P264-P270-P301+P312a-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,4474
Beilstein
1738385
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
YI3500000

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