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B23734 3-(Trifluoromethylthio)aniline, 96%

CAS Number
369-68-6
Synonyms
3-Aminophenyl trifluoromethyl sulfide

Stock No. Size Price ($) Quantity Availability
B23734-03 1g 75.70
B23734-06 5g 307.00
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3-(Trifluoromethylthio)aniline, 96%

MDL
MFCD00190130
EINECS
206-722-4

Chemical Properties

Formula
C7H6F3NS
Formula Weight
193.19
Boiling Point
221-224°
Flash Point
103°(218°F)
Density
1.348
Refractive Index
1.5220
Storage & Sensitivity
Ambient temperatures.
Solubility
Immiscible with water.

Applications

3-(Trifluoromethylthio)aniline is used as an intermediate in organic synthesis. It is also involved in the regioselective Friedel-Crafts alkylation in hexafluoroacetone sesquihydrate.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Masciadri, R.; Kamer, M.; Nock, N. Regioselective Friedel-Crafts Alkylation of Anilines and Amino-Substituted Heteroarenes with Hexafluoroacetone Sesquihydrate. Eur. J. Org. Chem. 2003, 2003 (21), 4286-4291.

Manoury, P. M.; Dumas, A. P.; Najer, H.; Branceni, D.; Prouteau, M.; Lefevre-Borg, F. M. Synthesis and analgesic activities of some (4-substituted phenyl-1-piperazinyl)alkyl 2-aminobenzoates and 2-aminonicotinates. J. Med. Chem. 1979, 22 (5), 554-559.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
No

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