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369-68-6 - 3-(Trifluoromethylthio)aniline, 96% - 3-Aminophenyl trifluoromethyl sulfide - B23734 - Alfa Aesar

B23734 3-(Trifluoromethylthio)aniline, 96%

CAS Number
369-68-6
Synonyms
3-Aminophenyl trifluoromethyl sulfide

Size Price ($) Quantity Availability
1g 80.80
5g 330.00
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3-(Trifluoromethylthio)aniline, 96%

MDL
MFCD00190130
EINECS
206-722-4

Chemical Properties

Formula
C7H6F3NS
Formula Weight
193.19
Boiling Point
221-224°
Flash Point
103°(218°F)
Density
1.348
Refractive Index
1.5220
Solubility
Immiscible with water.

Applications

3-(Trifluoromethylthio)aniline is used as an intermediate in organic synthesis. It is also involved in the regioselective Friedel-Crafts alkylation in hexafluoroacetone sesquihydrate.

Notes

Incompatible with strong oxidizing agents and strong bases.

Literature References

Masciadri, R.; Kamer, M.; Nock, N. Regioselective Friedel-Crafts Alkylation of Anilines and Amino-Substituted Heteroarenes with Hexafluoroacetone Sesquihydrate. Eur. J. Org. Chem. 2003, 2003 (21), 4286-4291.

Manoury, P. M.; Dumas, A. P.; Najer, H.; Branceni, D.; Prouteau, M.; Lefevre-Borg, F. M. Synthesis and analgesic activities of some (4-substituted phenyl-1-piperazinyl)alkyl 2-aminobenzoates and 2-aminonicotinates. J. Med. Chem. 1979, 22 (5), 554-559.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332-H315-H319

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P301+P312a-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2930.90
TSCA
No

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