B23834 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%
SDS
| Size | Price ($) | Quantity | Availability |
|---|---|---|---|
| 5g | 47.90 |
|
|
| 25g | 172.00 |
|
|
| 100g | 648.00 |
|
|
3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%
Chemical Properties
Applications
3,5-Di-tert-butyl-2-hydroxybenzaldehyde is used in the synthesis of Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose, chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenyl acetylene to imines, chiral oxazolidine ligand for the enantioselective addition of diethyl zinc to aldehydes and tin Schiff base complexes with histidine analogues. It has antibacterial activity and is used in the preparation nickel complexes. It is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).
Notes
Literature References
Yan S and Klemm D. Mild and efficient synthesis of 5, 6-diamino-5, 6-dideoxy-1, 2-O-isopropylidene-3- O -methyl-ß-l-idofuranose: precursor of the first carbohydrate-derived chiral Mn (III)-salen complex. Tetrahedron.,2002,58(50), 10065-10071.
Ariadna Garza-Ortiz, et al. Novel Organotin(IV) Schiff Base Complexes with Histidine Derivatives: Synthesis, Characterization, and Biological Activity.Bioinorg Chem Appl.,2013,2013(6), 502713.
GHS Hazard and Precautionary Statements
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P260-P201-P280g-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
