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2043-61-0 - Cyclohexanecarboxaldehyde, 97% - Hexahydrobenzaldehyde - B23837 - Alfa Aesar

B23837 Cyclohexanecarboxaldehyde, 97%

CAS Number
2043-61-0
Synonyms
Hexahydrobenzaldehyde

Size Price ($) Quantity Availability
25g 53.25
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Cyclohexanecarboxaldehyde, 97%

MDL
MFCD00001457
EINECS
218-057-7

Chemical Properties

Formula
C7H12O
Formula Weight
112.17
Melting point
34-35°
Boiling Point
161-163°
Flash Point
40°(105°F)
Density
0.930
Refractive Index
1.4500
Sensitivity
Air Sensitive
Solubility
Soluble in chloroform, ether, alcohol. Slightly soluble in water.

Applications

Cyclohexanecarboxaldehyde is used for the synthesis of poly(vinyl cyclohexanal). It was used as model substrate in the synthesis of propargylamines using Fe3O4 nanoparticles as catalyst. It was employed in an aldol reaction with ethyl diazoacetate catalyzed by basic, nanoparticulate magnesium oxide leading to α-diazo-β-hydroxyesters.

Notes

Air sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible material is strong oxidizing agents.

Literature References

Peter N. Kao; Paul H. Turner. Conformational study of cyclohexanecarboxaldehyde by microwave spectroscopy. J. Am. Chem. Soc. 1979, 101 (16), 4497-4499.

Hassan M. Badawi. An ab initio study of internal rotation in cyclohexanecarboxaldehyde and cyclohexanecarboxylic acid fluoride and chloride. J. Org. Chem. 1996, 369 (1-3), 75-83.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
878306
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2912.29
TSCA
No

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