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B23876 tert-Butylhydrazine hydrochloride, 98%

CAS Number
7400-27-3
Synonyms

Stock No. Size Price ($) Quantity Availability
B23876-14 25g 28.80
B23876-22 100g 68.60
B23876-36 500g 215.00
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tert-Butylhydrazine hydrochloride, 98%

MDL
MFCD00012947
EINECS
231-001-6

Chemical Properties

Formula
(CH3)3CNHNH2•HCl
Formula Weight
124.61
Melting point
ca 192° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Solubility in water (almost transparency). Soluble in DMSO and methanol.

Applications

It is used in organic synthesis for aromatic nucleophilic N-N exchange reaction. tert-Butylhydrazine Hydrochloride is also used in the preparation of insect growth regulator. tert-Butylhydrazine hydrochloride was used in the synthesis of diphosphinohydrazines, 5-amino-1-tert-butyl-3-(p-chlorophenyl)-4-cyanopyrazole and 1,3,4,5-tetrasubstituted pyrazole derivatives.

Notes

Hygroscopic. Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Protect from humidity and water.

Literature References

Clarissa P. Frizzo, et al. Ionic liquid effects on the reaction of β-enaminones and tert-butylhydrazine and applications for the synthesis of pyrazoles.Catal. Commun..,2009,10(15), 1967-1970.

Yoshihiro Sawada, et al. Synthesis and insecticidal activity of benzoheterocyclic analogues of N?-benzoyl-N-(tert-butyl)benzohydrazide: Part 3. Modification of N-tert-butylhydrazine moiety.Pest Management Science.,2003,59(1), 49-57.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3651224
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
MV2841000

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