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B23998 3-Bromopropionitrile, 97%

CAS Number
2417-90-5
Synonyms
2-Cyanoethyl bromide

Stock No. Size Price ($) Quantity Availability
B23998-14 25g 23.50
B23998-22 100g 83.60
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3-Bromopropionitrile, 97%

MDL
MFCD00001951
EINECS
219-332-4

Chemical Properties

Formula
BrCH2CH2CN
Formula Weight
133.98
Boiling Point
200°
Flash Point
97°(206°F)
Density
1.615
Refractive Index
1.4810
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ethanol, ether.

Applications

3-Bromopropionitrile was used as the initiator in the atom transfer radical polymerization of acrylonitrile. It was used in coupling reactions of a number of aromatic and heteroaromatic phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite.

Notes

Store in a cool, dry place in tightly closed container. Store at room temperature. Incompatible with oxidizing agents.

Literature References

Dora Demeter; Philippe Blanchard; Ion Grosu; Jean Roncali. Electropolymerization of crown-annelated bithiophenes. Electrochemistry Communications. 2007, 9 (7), 1587-1591.

Edward S. Binkley; Clayton H. Heathcock. Regiospecific alkylation of enolate ions in liquid ammonia-tetrahydrofuran. J. Org. Chem. 1975, 40 (15), 2156-2160.

Reagent for protection of thiols (K 2 CO 3 - DMF) as S-2-cyanoethyl thioethers. Deprotection can be effected with conc. ammonia: Nucleic Acids Res., 19, 5719 (1991), K 2 CO 3 /NaBH 4 in DMF: Tetrahedron Lett., 27, 203 (1986), or KO-t-Bu - DMF: Bull. Chem. Soc. Jpn., 63, 829 (1990).

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1738565
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
UG1050000

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