I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.
5-Aminotetrazole monohydrate is a useful reagent in condensation reactions to form pyrimidines.
Thomas M. Klapötke and Jörg Stierstorfer. Nitration Products of 5-Amino-1H-tetrazole and Methyl-5-amino-1H-tetrazoles - Structures and Properties of Promising Energetic Materials. Helvetica Chimica Acta. 2007, 90 (11), 2132-2150.
Anton Hammerl; Michael A. Hiskey; Gerhard Holl; Thomas M. Klapötke; Kurt Polborn; Jörg Stierstorfer; and Jan J. Weigand. Azidoformamidinium and Guanidinium 5,5-Azotetrazolate Salts. Chem. Mater. 2005, 17 (14), 3784-3793.
Aldehydes can be converted to isonitriles via imine formation, catalytic reduction and hypobromite oxidation of the tetrazole ring: Angew. Chem. Int. Ed., 15, 113 (1976): Org. Synth. Coll., 7, 27 (1990):
Hazard Statements: H228-H240-H315-H319-H335
Flammable solid. Heating may cause an explosion. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P210-P220-P305+P351+P338-P370+P380+P375-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.