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B24064 1,4-Benzenediboronic acid, 96%

CAS Number
4612-26-4
Synonyms
1,4-Phenylenediboronic acid

Stock No. Size Price ($) Quantity Availability
B24064-03 1g 34.80
B24064-06 5g 99.00
B24064-14 25g 413.00
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1,4-Benzenediboronic acid, 96%

MDL
MFCD00236018

Chemical Properties

Formula
C6H8B2O4
Formula Weight
165.75
Melting point
>300°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water 2.5%.

Applications

It is used for palladium-catalyzed sequential alkenylation and conjugate addition reactions, scholl cyclizations, Suzuki-Miyaura cross-coupling reactions. It is also used in the preparation of indolizine derivatives as OLEDs, in organic thin-film transistors, Fluorescence and solution-processable coordination polymers.

Notes

Store in a cool, dry place in tightly closed container. Store at room temperature. Incompatible with oxidizing agents.

Literature References

Byung Seok Kim; Sun Young Lee; So Won Youn. Pd-catalyzed sequential C-C and C-N bond formations for the synthesis of N-heterocycles: exploiting protecting group-directed C-H activation under modified reaction conditions. Chemistry An Asian Journal. 2011, 6 (8), 1952-1957.

Supratim Basak; Pramiti Hui; Sathyanarayana Boodida; Rajadurai Chandrasekar. Micropatterning of metallopolymers: syntheses of back-to-back coupled octylated 2,6-bis(pyrazolyl)pyridine ligands and their solution-processable coordination polymers. Journal of Organic Chemistry. 2012, 77 (7), 3620-3626.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2836921
Harmonized Tariff Code
2931.90
TSCA
No

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