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4612-26-4 - 1,4-Benzenediboronic acid, 96% - 1,4-Phenylenediboronic acid - B24064 - Alfa Aesar

B24064 1,4-Benzenediboronic acid, 96%

CAS Number
4612-26-4
Synonyms
1,4-Phenylenediboronic acid

Size Price ($) Quantity Availability
1g 26.80
5g 95.85
25g 327.20
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1,4-Benzenediboronic acid, 96%

MDL
MFCD00236018

Chemical Properties

Formula
C6H8B2O4
Formula Weight
165.75
Melting point
>300°
Solubility
Soluble in water 2.5%.

Applications

It is used for palladium-catalyzed sequential alkenylation and conjugate addition reactions, scholl cyclizations, Suzuki-Miyaura cross-coupling reactions. It is also used in the preparation of indolizine derivatives as OLEDs, in organic thin-film transistors, Fluorescence and solution-processable coordination polymers.

Notes

Store in a cool, dry place in tightly closed container. Store at room temperature. Incompatible with oxidizing agents.

Literature References

Byung Seok Kim; Sun Young Lee; So Won Youn. Pd-catalyzed sequential C-C and C-N bond formations for the synthesis of N-heterocycles: exploiting protecting group-directed C-H activation under modified reaction conditions. Chemistry An Asian Journal. 2011, 6 (8), 1952-1957.

Supratim Basak; Pramiti Hui; Sathyanarayana Boodida; Rajadurai Chandrasekar. Micropatterning of metallopolymers: syntheses of back-to-back coupled octylated 2,6-bis(pyrazolyl)pyridine ligands and their solution-processable coordination polymers. Journal of Organic Chemistry. 2012, 77 (7), 3620-3626.

GHS Hazard and Precautionary Statements

Hazard Statements: H302

Harmful if swallowed.

Precautionary Statements: P264-P270-P301+P312-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2836921
Harmonized Tariff Code
2931.90
TSCA
No

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