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626-60-8 - 3-Chloropyridine, 99% - B24316 - Alfa Aesar

B24316 3-Chloropyridine, 99%

CAS Number
626-60-8
Synonyms

Size Price ($) Quantity Availability
10g 23.31
50g 69.32
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3-Chloropyridine, 99%

MDL
MFCD00006375
EINECS
210-955-7

Chemical Properties

Formula
C5H4ClN
Formula Weight
113.55
Boiling Point
147-149°
Flash Point
53°(127°F)
Density
1.205
Refractive Index
1.5330
Solubility
Soluble in water 10 g/L.

Applications

3-Chloropyridine is used as a pharmaceutical intermediate. It can be used to produce 3-chloro-pyridine-1-oxide.

Notes

Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

Literature References

S. M. Angel and D. D. Archibald. Near-Infrared Surface-Enhanced Raman Spectra of 3-Picoline and 3-Chloropyridine on a Copper Electrode. Applied Spectroscopy. 1989, 43 (6), 1097-1099.

José M. Moreno; Maria A. Aramendía; Alberto Marinas; José M. Marinas; Francisco J. Urbano. Hydrodechlorination of 3-chloropyridine and chlorobenzene in methanol solution over alkali-modified zirconia-supported palladium catalysts. Applied Catalysis B: Environmental. 2005, 59 (3-4), 275-283.

With n-BuLi and TMEDA at -60 o, lithiation occurs predominantly at the 2-position, with some 4-lithiation: Tetrahedron, 39, 2009 (1983). With LDA at -60 o, exclusive 4-lithiation occurs: J. Org. Chem., 47, 2633 (1982); Heterocycles, 35, 151 (1993).

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H226-H302-H335

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour. Harmful if swallowed. May cause respiratory irritation.

Precautionary Statements: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
105744
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
US6125000

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