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B24316 3-Chloropyridine, 99%

CAS Number
626-60-8
Synonyms

Stock No. Size Price ($) Quantity Availability
B24316-09 10g 27.70
B24316-18 50g 71.20
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3-Chloropyridine, 99%

MDL
MFCD00006375
EINECS
210-955-7

Chemical Properties

Formula
C5H4ClN
Formula Weight
113.55
Boiling Point
147-149°
Flash Point
53°(127°F)
Density
1.205
Refractive Index
1.5330
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water 10 g/L.

Applications

3-Chloropyridine is used as a pharmaceutical intermediate. It can be used to produce 3-chloro-pyridine-1-oxide.

Notes

Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

Literature References

S. M. Angel and D. D. Archibald. Near-Infrared Surface-Enhanced Raman Spectra of 3-Picoline and 3-Chloropyridine on a Copper Electrode. Applied Spectroscopy. 1989, 43 (6), 1097-1099.

José M. Moreno; Maria A. Aramendía; Alberto Marinas; José M. Marinas; Francisco J. Urbano. Hydrodechlorination of 3-chloropyridine and chlorobenzene in methanol solution over alkali-modified zirconia-supported palladium catalysts. Applied Catalysis B: Environmental. 2005, 59 (3-4), 275-283.

With n-BuLi and TMEDA at -60 o, lithiation occurs predominantly at the 2-position, with some 4-lithiation: Tetrahedron, 39, 2009 (1983). With LDA at -60 o, exclusive 4-lithiation occurs: J. Org. Chem., 47, 2633 (1982); Heterocycles, 35, 151 (1993).

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H302-H315-H319-H335

Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
105744
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
US6125000

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