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86-52-2 - 1-(Chloromethyl)naphthalene, 94% - 1-Naphthylmethyl chloride - B24385 - Alfa Aesar

B24385 1-(Chloromethyl)naphthalene, 94%

CAS Number
86-52-2
Synonyms
1-Naphthylmethyl chloride

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1-(Chloromethyl)naphthalene, 94%

MDL
MFCD00004042
EINECS
201-678-2

Chemical Properties

Formula
C11H9Cl
Formula Weight
176.65
Melting point
31-33°
Boiling Point
291-292°
Flash Point
132°(270°F)
Density
1.181
Refractive Index
1.6370
Solubility
Insoluble in water.

Applications

1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.

Notes

Store at room temperature. Incompatible with oxidizing agents and bases.

Literature References

Bo Peng.; Sheng Zhang.; Xiaoqiang Yu.; Xiujuan Feng.; Ming Bao. Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization. Org. Lett. 2011, 13 (19), 5402-5405 .

Rajendra P. Singh.; Jean'ne M. Shreeve. Recent Highlights in Electrophilic Fluorination with 1-Chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate). Acc. Chem. Res. 2004, 37 (1),31-44 .

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H314-H318

Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
636885
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
QJ2800000

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