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B24385 1-(Chloromethyl)naphthalene, 94%

CAS Number
86-52-2
Synonyms
1-Naphthylmethyl chloride

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Bulk/Specialty

1-(Chloromethyl)naphthalene, 94%

MDL
MFCD00004042
EINECS
201-678-2

Chemical Properties

Formula
C11H9Cl
Formula Weight
176.65
Melting point
31-33°
Boiling Point
291-292°
Flash Point
132°(270°F)
Density
1.181
Refractive Index
1.6370
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.

Notes

Store at room temperature. Incompatible with oxidizing agents and bases.

Literature References

Bo Peng.; Sheng Zhang.; Xiaoqiang Yu.; Xiujuan Feng.; Ming Bao. Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization. Org. Lett. 2011, 13 (19), 5402-5405 .

Rajendra P. Singh.; Jean'ne M. Shreeve. Recent Highlights in Electrophilic Fluorination with 1-Chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate). Acc. Chem. Res. 2004, 37 (1),31-44 .

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312-H314

Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
636885
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
QJ2800000

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