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22323-82-6 - (S)-(+)-2,3-O-Isopropylideneglycerol, 98% - (S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol - B24488 - Alfa Aesar

B24488 (S)-(+)-2,3-O-Isopropylideneglycerol, 98%

CAS Number
22323-82-6
Synonyms
(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol

Size Price ($) Quantity Availability
2g 36.97
10g 146.37
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(S)-(+)-2,3-O-Isopropylideneglycerol, 98%

MDL
MFCD00063239
EINECS
244-910-8

Chemical Properties

Formula
C6H12O3
Formula Weight
132.18
Boiling Point
82-83°/14mm
Flash Point
80°(176°F)
Density
1.066
Refractive Index
1.4350
Solubility
Miscible with water and chloroform.

Applications

(S)-(+)-2,3-O-Isopropylideneglycerol acts as a MEK inhibitor with antitumor activity. It is also employed in the preparation of a chiral allylic triol through extrusion of sulfur dioxide from an alfa,beta-epoxysulfone.

Notes

Store in a cool place. Incompatible with acids and strong oxidizing agents.

Literature References

Nanda, M. R.; Zhang, Y.; Yuan, Z.; Qin, W.; Ghaziaskar, H. S.; Xu, C. C. Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A review. Renew. Sust. Energ. Rev. 2016, 56, 1022-1031.

Wu, G.; Wang, P. Intramolecular Enantiomerism in S (+) 2,2-dimethyl-1,3-dioxolane-4-methanol: The Interpretation of Raman Optical Activity Intensity. Chirality 2015, 27 (11), 820-825.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,5213
Beilstein
80118
Harmonized Tariff Code
2932.99
TSCA
No

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