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B24536 1-Indanol, 98%

CAS Number
6351-10-6
Synonyms
1-Hydroxyindane

Stock No. Size Price ($) Quantity Availability
B24536-06 5g 37.50
B24536-14 25g 127.00
B24536-18 50g 214.00
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1-Indanol, 98%

MDL
MFCD00003797
EINECS
224-230-8

Chemical Properties

Formula
C9H10O
Formula Weight
134.18
Melting point
50-54°
Boiling Point
128°/12mm
Flash Point
145°(293°F)
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water 10 g/L at 20°C, ethanol, benzene.

Applications

1-Indanol derivative was found to be an efficient ligand for the palladium-catalyzed asymmetric Heck reaction. It is used as pharmaceutical intermediate.

Notes

Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

Literature References

Jonas Altnöder; Aude Bouchet; Juhyon J Lee; Katharina E Otto; Martin A Suhm; Anne Zehnacker-Rentien. Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters. Physical Chemistry Chemical Physics. 2013, 15 (25), 10167-10180.

Attila Felinger; Dongmei Zhou; Georges Guiochon. Determination of the single component and competitive adsorption isotherms of the 1-indanol enantiomers by the inverse method. Journal of Chromatography A. 2003, 1005 (1-2), 35-49.

Oxidation to the indanone can be effected with acetone in the presence of K2CO3, catalyzed by Dichlorotris(triphenyl­phosphine)­ruthenium(II)­, L00373: J. Chem. Soc., Chem. Commun., 337 (1992).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2042960
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2906.29
TSCA
No

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