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1-Indanol derivative was found to be an efficient ligand for the palladium-catalyzed asymmetric Heck reaction. It is used as pharmaceutical intermediate.
Jonas Altnöder; Aude Bouchet; Juhyon J Lee; Katharina E Otto; Martin A Suhm; Anne Zehnacker-Rentien. Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters. Physical Chemistry Chemical Physics. 2013, 15 (25), 10167-10180.
Attila Felinger; Dongmei Zhou; Georges Guiochon. Determination of the single component and competitive adsorption isotherms of the 1-indanol enantiomers by the inverse method. Journal of Chromatography A. 2003, 1005 (1-2), 35-49.
Oxidation to the indanone can be effected with acetone in the presence of K2CO3, catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II), L00373: J. Chem. Soc., Chem. Commun., 337 (1992).
Hazard Statements: H302-H315-H319-H335
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant