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B24614 2-Bromo-3,3,3-trifluoro-1-propene, 97%

CAS Number

Stock No. Size Price ($) Quantity Availability
B24614-06 5g 59.10
B24614-14 25g 190.00
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2-Bromo-3,3,3-trifluoro-1-propene, 97%


Chemical Properties

Formula Weight
Refractive Index
Storage & Sensitivity
Ambient temperatures.
Soluble in most organic solvents, immiscible with water.


It is used as intermediate in production of organ fluorine compounds & as a monomer in fluoropolymer production. It is used as a trifluoromethylated synthetic building block for the synthesis of trifluoromethyl-substituted molecules.


Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

Literature References

Junji Ichikawa; Yuichiro Ishibashi; Hiroki Fukui. A novel synthesis of functionalized 1,1-difluoro-1-alkenes via isolable 2,2-difluorovinylsilanes. Tetrahedron Letters. 2003, 44 (4), 707-710.

Qi Chen; Xiao-Long Qiu; Feng-Ling Qing. Nucleophilic addition of 3,3,3-trifluoropropynyllithium to d-glyceraldimine: Concise synthesis of both enantiomers of 5,5,5-trifluoronorvaline. Journal of Fluorine Chemistry. 2007, 128 (10), 1182-1186.

Precursor of 1-(trifluoromethylvinyl) organometallic species which permit the introduction of this useful fragment into a variety of molecules. For a review, see: Tetrahedron, 50, 2993 (1994).

Treatment with LDA gives a trifluoromethylacetylene anion synthon which reacts with electrophiles to give trifluoromethylethynyl products: J. Fluorine Chem., 80, 145 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

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