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B24614 2-Bromo-3,3,3-trifluoro-1-propene, 97%

CAS Number

Stock No. Size Price ($) Quantity Availability
B24614-06 5g 60.80
B24614-14 25g 194.00
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2-Bromo-3,3,3-trifluoro-1-propene, 97%


Chemical Properties

Formula Weight
Refractive Index
Storage & Sensitivity
Ambient temperatures.
Soluble in most organic solvents, immiscible with water.


It is used as intermediate in production of organ fluorine compounds & as a monomer in fluoropolymer production. It is used as a trifluoromethylated synthetic building block for the synthesis of trifluoromethyl-substituted molecules.


Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

Literature References

Junji Ichikawa; Yuichiro Ishibashi; Hiroki Fukui. A novel synthesis of functionalized 1,1-difluoro-1-alkenes via isolable 2,2-difluorovinylsilanes. Tetrahedron Letters. 2003, 44 (4), 707-710.

Qi Chen; Xiao-Long Qiu; Feng-Ling Qing. Nucleophilic addition of 3,3,3-trifluoropropynyllithium to d-glyceraldimine: Concise synthesis of both enantiomers of 5,5,5-trifluoronorvaline. Journal of Fluorine Chemistry. 2007, 128 (10), 1182-1186.

Precursor of 1-(trifluoromethylvinyl) organometallic species which permit the introduction of this useful fragment into a variety of molecules. For a review, see: Tetrahedron, 50, 2993 (1994).

Treatment with LDA gives a trifluoromethylacetylene anion synthon which reacts with electrophiles to give trifluoromethylethynyl products: J. Fluorine Chem., 80, 145 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements: H335-H336

May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P261-P271-P304+P340-P312-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Dispose of contents/ container to an approved waste disposal plant

Other References

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