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B24670 3-Bromo-4-methylaniline, 97%

CAS Number
7745-91-7
Synonyms
4-Amino-2-bromotoluene
3-Bromo-p-toluidine

Stock No. Size Price ($) Quantity Availability
B24670-06 5g 39.20
B24670-14 25g 140.00
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3-Bromo-4-methylaniline, 97%

MDL
MFCD00134176
EINECS
231-807-8

Chemical Properties

Formula
C7H8BrN
Formula Weight
186.06
Melting point
25-28°
Boiling Point
254-257°
Flash Point
>110°(230°F)
Refractive Index
1.6115
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

3-Bromo-4-methylaniline is used in the synthesis of 1,7-dihalo Tröger?s base isomers. It is suitable for use to investigate the reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations with O2 by ion-trap mass spectrometry.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Matthew B Prendergast.; Phillip A Cooper.; Benjamin B Kirk.; Gabriel da Silva.; Stephen J Blanksby.; Adam J Trevitt. Hydroxyl radical formation in the gas phase oxidation of distonic 2-methylphenyl radical cations. Physical Chemistry Chemical Physics. 2013, 15 (47), 20577-20584.

M. S. Carpenter.; W. M. Easter. The Isopropyl Cresols. J. Org. Chem. 1955, 20 (4), 401-411.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1562057
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.43
TSCA
No
RTECS
XU4375000

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