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7745-91-7 - 3-Bromo-4-methylaniline, 97% - 4-Amino-2-bromotoluene - 3-Bromo-p-toluidine - B24670 - Alfa Aesar

B24670 3-Bromo-4-methylaniline, 97%

CAS Number
7745-91-7
Synonyms
4-Amino-2-bromotoluene
3-Bromo-p-toluidine

Size Price ($) Quantity Availability
5g 38.70
25g 145.00
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3-Bromo-4-methylaniline, 97%

MDL
MFCD00134176
EINECS
231-807-8

Chemical Properties

Formula
C7H8BrN
Formula Weight
186.06
Melting point
25-28°
Boiling Point
254-257°
Flash Point
>110°(230°F)
Refractive Index
1.6115
Solubility
Insoluble in water.

Applications

3-Bromo-4-methylaniline is used in the synthesis of 1,7-dihalo Tröger?s base isomers. It is suitable for use to investigate the reactions of distonic 4-(N,N,N-trimethylammonium)-2-methylphenyl and 5-(N,N,N-trimethylammonium)-2-methylphenyl radical cations with O2 by ion-trap mass spectrometry.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Matthew B Prendergast.; Phillip A Cooper.; Benjamin B Kirk.; Gabriel da Silva.; Stephen J Blanksby.; Adam J Trevitt. Hydroxyl radical formation in the gas phase oxidation of distonic 2-methylphenyl radical cations. Physical Chemistry Chemical Physics. 2013, 15 (47), 20577-20584.

M. S. Carpenter.; W. M. Easter. The Isopropyl Cresols. J. Org. Chem. 1955, 20 (4), 401-411.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H315-H319

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280h-P305+P351+P338-P309-P310a-P302+P352a

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: IF ON SKIN:

Other References

Beilstein
1562057
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.43
TSCA
No
RTECS
XU4375000

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