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B24764 Benzhydryl chloride, 98%

CAS Number
90-99-3
Synonyms
Chlorodiphenylmethane
Diphenylmethyl chloride

Stock No. Size Price ($) Quantity Availability
B24764-14 25g 29.10
B24764-22 100g 93.10
B24764-36 500g 388.00
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Benzhydryl chloride, 98%

MDL
MFCD00000855
EINECS
202-031-7

Chemical Properties

Formula
C13H11Cl
Formula Weight
202.69
Melting point
17-20°
Boiling Point
139-140°/3mm
Flash Point
160°(320°F)
Density
1.14
Refractive Index
1.5950
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Benzhydryl chloride was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives.

Notes

Store in a tightly sealed container. Store away from oxidizing agents, bases.

Literature References

Shota Niibayashi; Hitoshi Hayakawa; Ren-Hua Jin; Hideo Nagashima. Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization. Chemical Communications. 2007, (18), 337-342.

N Kawasaki; H Miyataka; M Nishiki; H Matsumoto; N Inagaki; H Nagai; T Satoh. Synthesis of trimethylhydroquinone derivatives as anti-allergic agents with anti-oxidative actions. Chemical & Pharmaceutical Bulletin. 1999, 47 (2), 177-181.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H314

May be corrosive to metals. Causes severe skin burns and eye damage.

Precautionary Statements: P234-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
607925
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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