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90-99-3 - Benzhydryl chloride, 98% - Chlorodiphenylmethane - Diphenylmethyl chloride - B24764 - Alfa Aesar

B24764 Benzhydryl chloride, 98%

CAS Number
90-99-3
Synonyms
Chlorodiphenylmethane
Diphenylmethyl chloride

Size Price ($) Quantity Availability
25g 27.20
100g 87.70
500g 366.00
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Benzhydryl chloride, 98%

MDL
MFCD00000855
EINECS
202-031-7

Chemical Properties

Formula
C13H11Cl
Formula Weight
202.69
Melting point
17-20°
Boiling Point
139-140°/3mm
Flash Point
160°(320°F)
Density
1.14
Refractive Index
1.5950
Solubility
Insoluble in water.

Applications

Benzhydryl chloride was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives.

Notes

Store in a tightly sealed container. Store away from oxidizing agents, bases.

Literature References

Shota Niibayashi; Hitoshi Hayakawa; Ren-Hua Jin; Hideo Nagashima. Reusable and environmentally friendly ionic trinuclear iron complex catalyst for atom transfer radical polymerization. Chemical Communications. 2007, (18), 337-342.

N Kawasaki; H Miyataka; M Nishiki; H Matsumoto; N Inagaki; H Nagai; T Satoh. Synthesis of trimethylhydroquinone derivatives as anti-allergic agents with anti-oxidative actions. Chemical & Pharmaceutical Bulletin. 1999, 47 (2), 177-181.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
607925
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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