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4606-07-9 - Ethyl cyclopropanecarboxylate, 98% - Cyclopropanecarboxylic acid ethyl ester - B24870 - Alfa Aesar

B24870 Ethyl cyclopropanecarboxylate, 98%

CAS Number
4606-07-9
Synonyms
Cyclopropanecarboxylic acid ethyl ester

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Ethyl cyclopropanecarboxylate, 98%

MDL
MFCD00001282
EINECS
225-010-4

Chemical Properties

Formula
C6H10O2
Formula Weight
114.15
Boiling Point
133-134°
Flash Point
18°(64°F)
Density
0.960
Refractive Index
1.4200
Solubility
Not miscible in water.

Applications

Ethyl cyclopropanecarboxylate is a reagent used in the addition of cyclopropane. It acts as annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible materials are oxidizing agents.

Literature References

Harold W. Pinnick; Stephen P. Brown; Elizabeth A. McLean; Linwood W. ZollerIII. Friedel-Crafts reactions of ethyl cyclopropanecarboxylate. J. Org. Chem.1981, 46, (18), 3758-3760.

Gary M. Lampman; Deane A. Horne; Gordon D. Hager. Convenient syntheses of cyclopropanecarboxylic acid, ethyl cyclopropanecarboxylate, cyclopropanecarbonitrile, and nitrocyclopropane. J. Chem. Eng. Data.1969, 14, (3), 396-397.

Annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions: J. Am. Chem. Soc., 99, 5508 (1977); J. Org. Chem., 46, 3758 (1981):

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2039752
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2916.20
TSCA
No

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