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B24870 Ethyl cyclopropanecarboxylate, 98%

CAS Number
4606-07-9
Synonyms
Cyclopropanecarboxylic acid ethyl ester

Stock No. Size Price ($) Quantity Availability
B24870-14 25g 38.30
B24870-22 100g 95.90
B24870-36 500g 405.00
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Ethyl cyclopropanecarboxylate, 98%

MDL
MFCD00001282
EINECS
225-010-4

Chemical Properties

Formula
C6H10O2
Formula Weight
114.15
Boiling Point
133-134°
Flash Point
18°(64°F)
Density
0.960
Refractive Index
1.4200
Storage & Sensitivity
Ambient temperatures.
Solubility
Not miscible in water.

Applications

Ethyl cyclopropanecarboxylate is a reagent used in the addition of cyclopropane. It acts as annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible materials are oxidizing agents.

Literature References

Harold W. Pinnick; Stephen P. Brown; Elizabeth A. McLean; Linwood W. ZollerIII. Friedel-Crafts reactions of ethyl cyclopropanecarboxylate. J. Org. Chem.1981, 46, (18), 3758-3760.

Gary M. Lampman; Deane A. Horne; Gordon D. Hager. Convenient syntheses of cyclopropanecarboxylic acid, ethyl cyclopropanecarboxylate, cyclopropanecarbonitrile, and nitrocyclopropane. J. Chem. Eng. Data.1969, 14, (3), 396-397.

Annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions: J. Am. Chem. Soc., 99, 5508 (1977); J. Org. Chem., 46, 3758 (1981):

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302+H312+H332

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P312-P330-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2039752
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2916.20
TSCA
No

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