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1-Thionaphthol is used to produce the di-naphthyl disulfide. It is also used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
Xuhong Qian; Tian-Bao Huang; Dong-zhi Wei; Dong-Hui Zhu; Zhub and Wei Yao. Interaction of naphthyl heterocycles with DNA: effects of thiono and thio groups. J. Chem. Soc., Perkin Trans. 2.2000, 715-718.