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B24951 cis-5-Norbornene-endo-2,3-dicarboxylic anhydride, 97%

CAS Number
129-64-6
Synonyms
Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride
Carbic anhydride

Stock No. Size Price ($) Quantity Availability
B24951-06 5g 36.40
B24951-14 25g 115.00
B24951-22 100g 339.00
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cis-5-Norbornene-endo-2,3-dicarboxylic anhydride, 97%

MDL
MFCD00151106
EINECS
204-957-7

Chemical Properties

Formula
C9H8O3
Formula Weight
164.16
Melting point
164-167°
Density
1.417
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
It decomposes in water.

Applications

cis-5-Norbornene-endo-2,3-dicarboxylic anhydride is used as an organic chemical synthesis intermediate.

Notes

Moisture sensitive. Incompatible with oxidizing agents.

Literature References

Cihangir Tanyeli; Aysegul Gumus. Synthesis of polymer-supported TEMPO catalysts and their application in the oxidation of various alcohols. Tetrahedron Letters. 2003, 44,(8), 1639-1642.

 

Didier Villemin; Bouchta Labiad; Andre Loupy. Clay catalysis: A convenient and rapid formation of anhydride from carboxylic acid and isopropenyl acetate under microwave irradiation. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 1993, 23,(4), 419-424.

GHS Hazard and Precautionary Statements

Hazard Statements: H317-H318-H334

May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Precautionary Statements: P261-P272-P280-P285-P302+P352-P304+P341-P305+P351+P338-P310-P333+P313-P342+P311-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. If skin irritation or rash occurs: Get medical advice/attention. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1796
Beilstein
83657
Harmonized Tariff Code
2917.20
TSCA
No
RTECS
DT5600000

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