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14205-39-1 - Methyl 3-aminocrotonate, 97% - 3-Aminocrotonic acid methyl ester - Methyl 3-aminobut-2-enoate - B24953 - Alfa Aesar

B24953 Methyl 3-aminocrotonate, 97%

CAS Number
14205-39-1
Synonyms
3-Aminocrotonic acid methyl ester
Methyl 3-aminobut-2-enoate

Size Price ($) Quantity Availability
100g 28.50
500g 97.20
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Methyl 3-aminocrotonate, 97%

MDL
MFCD00008072
EINECS
238-056-5

Chemical Properties

Formula
C5H9NO2
Formula Weight
115.13
Melting point
81-85°
Boiling Point
122°/42mm
Flash Point
91°(195°F)
Sensitivity
Hygroscopic

Literature References

Reaction with aryldiazonium salts gave, instead of the expected triazene, methyl 2-arylhydrazono-3-ketobutyrates, formed by electrophilic attack at the ɑ-carbon and hydrolysis of the resulting imine: Can. J. Chem., 73, 169 (1995).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H332-H315-H319-H317-H335

Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P363-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
956592
Harmonized Tariff Code
2922.49
TSCA
Yes
RTECS
EM9092500

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