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B24959 m-Xylylene dibromide, 97%

CAS Number
626-15-3
Synonyms
1,3-Bis(bromomethyl)benzene
alpha,alpha'-Dibromo-m-xylene

Stock No. Size Price ($) Quantity Availability
B24959-09 10g 51.90
B24959-18 50g 207.00
B24959-30 250g 834.00
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m-Xylylene dibromide, 97%

MDL
MFCD00000178
EINECS
210-931-6

Chemical Properties

Formula
C8H8Br2
Formula Weight
263.96
Melting point
74-76°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

It is used in preparation of four novel dinuclear half-titanocenes with meta- and orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.

Notes

Store in a cool, dry conditions, in well sealed conditions. Store away from oxidizing agents, active metals, bases.

Literature References

Murray V. Baker; David H. Brown; Valerie J. Hesler; Brian W. Skelton and Allan H. White. Synthesis of a Bis(N-heterocyclic carbene)palladium Complex via Oxidative Addition of a C-C Bond in a Biimidazolium Ion. Organometallics. 2007, 26 (2), 250-252.

Keiiti Sisido; Nobuo Kusano; Ryôzi Noyori; Yôko Nozaki; Masatosi Simosaka and Hitosi Nozaki. Polycondensation of xylylene dibromides by transition metals in water suspension. Journal of Polymer Science Part A: General Papers. 1963, 1 (6), 2101-2107.

Reductive coupling has been used in a relatively high-yielding route to [2,2]-m-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc. Perkin 1, 2029 (1991).

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H314-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
971085
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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