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626-15-3 - m-Xylylene dibromide, 97% - 1,3-Bis(bromomethyl)benzene - alpha,alpha'-Dibromo-m-xylene - B24959 - Alfa Aesar

B24959 m-Xylylene dibromide, 97%

CAS Number
626-15-3
Synonyms
1,3-Bis(bromomethyl)benzene
alpha,alpha'-Dibromo-m-xylene

Size Price ($) Quantity Availability
10g 48.40
50g 195.00
250g 794.00
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m-Xylylene dibromide, 97%

MDL
MFCD00000178
EINECS
210-931-6

Chemical Properties

Formula
C8H8Br2
Formula Weight
263.96
Melting point
74-76°
Solubility
Insoluble in water.

Applications

It is used in preparation of four novel dinuclear half-titanocenes with meta- and orthoxylene bridges as new metallocenes. It was used in the synthesis of dissymmetrical bis-macro cyclic salt.

Notes

Store in a cool, dry conditions, in well sealed conditions. Store away from oxidizing agents, active metals, bases.

Literature References

Murray V. Baker; David H. Brown; Valerie J. Hesler; Brian W. Skelton and Allan H. White. Synthesis of a Bis(N-heterocyclic carbene)palladium Complex via Oxidative Addition of a C-C Bond in a Biimidazolium Ion. Organometallics. 2007, 26 (2), 250-252.

Keiiti Sisido; Nobuo Kusano; Ryôzi Noyori; Yôko Nozaki; Masatosi Simosaka and Hitosi Nozaki. Polycondensation of xylylene dibromides by transition metals in water suspension. Journal of Polymer Science Part A: General Papers. 1963, 1 (6), 2101-2107.

Reductive coupling has been used in a relatively high-yielding route to [2,2]-m-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc. Perkin 1, 2029 (1991).

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P280-P305+P351+P338-P309-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor

Other References

Beilstein
971085
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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