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103-80-0 - Phenylacetyl chloride, 98% - B24987 - Alfa Aesar

B24987 Phenylacetyl chloride, 98%

CAS Number
103-80-0
Synonyms

Size Price ($) Quantity Availability
100g 35.30
500g 136.00
1000g 240.00
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Phenylacetyl chloride, 98%

MDL
MFCD00000729
EINECS
203-146-5

Chemical Properties

Formula
C8H7ClO
Formula Weight
154.60
Boiling Point
225°
Flash Point
102°(215°F)
Density
1.168
Refractive Index
1.5325
Sensitivity
Moisture Sensitive
Solubility
Miscible with alcohol and ether.

Applications

Phenylacetyl chloride is used in the preparation of 1,2-diphenyl-ethanone by reaction with iodobenzene using tetrabutylammonium tetrafluoroborate as a phase transfer catalyst. It is widely used in the chemical industry for manufacturing dyes and pharmaceutical products. It plays an important role in the preparation of penicillin. Further, it is used to prepare esters for flavorings.

Notes

Moisture sensitive. Store in a cool place.Incompatible with amines, most common metals, strong bases and strong oxidizing agents.

Literature References

Tao, Y.; Han, L.; Li, X.; Han, Y.; Liu, Z. Conformational stability and vibrational study of phenylacetyl chloride. J. Phys. Org. Chem. 2015, 28 (11), 703-711.

Hesping, L.; Biswas, A.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Studer, A. Stereoselective Lewis base catalyzed formal 1,3-dipolar cycloaddition of azomethine imines with mixed anhydrides. Chem. Sci. 2015, 6 (2), 1252-1257.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
742254
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2916.39
TSCA
Yes

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