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139-02-6 - Sodium phenoxide, 98% - Sodium phenylate - B25002 - Alfa Aesar

B25002 Sodium phenoxide, 98%

CAS Number
139-02-6
Synonyms
Sodium phenylate

Size Price ($) Quantity Availability
50g 58.60
250g 238.00
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Sodium phenoxide, 98%

MDL
MFCD00013134
EINECS
205-347-3

Chemical Properties

Formula
C6H5NaO
Formula Weight
116.09
Melting point
>300°
Sensitivity
Air Sensitive
Solubility
Very soluble in water, soluble in alcoholSoluble in water, acetone and alcohol.

Applications

Sodium phenoxide is used as a precursor to aryl ethers and involved in the preparation of phenyl ethers and metal phenolates. It serves as an antiseptic and used in organic synthesis.

Notes

Hygroscopic and air sensitive. Incompatible with oxidizing agents.

Literature References

Branchini, B. R.; Behney, C. E.; Southworth, T. L.; Fontaine, D. M.; Gulick, A. M.; Vinyard, D. J.; Brudvig, G. W. Experimental Support for a Single Electron-Transfer Oxidation Mechanism in Firefly Bioluminescence. J. Am. Chem. Soc. 2015, 137 (24), 7592-7595.

Zhang, W.; Fan, X.; Tian, W.; Chen, H.; Zhu, X.; Zhang, H. Preparation of a P(THF-co-PO)-b-PB-b-P(THF-co-PO) triblock copolymer via cationic ring-opening polymerization and its use as a thermoset polymer. RSC Adv. 2015, 5 (81), 66073-66081.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2907.11
TSCA
Yes
RTECS
SM8780000

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