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102-54-5 - Ferrocene, high purity, 99.5% - Bis(cyclopentadienyl)iron - Di(cyclopentadienyl)iron - B25007 - Alfa Aesar

B25007 Ferrocene, high purity, 99.5%

CAS Number
102-54-5
Synonyms
Bis(cyclopentadienyl)iron
Di(cyclopentadienyl)iron

Ferrocene, high purity, 99.5%

MDL
MFCD00001427
EINECS
203-039-3

Chemical Properties

Formula
C10H10Fe
Formula Weight
186.04
Melting point
173-174°
Boiling Point
249°
Density
1.490

Literature References

Readily undergoes electrophilic substitution reactions such as acylation, formylation, Mannich reaction, etc. For a review, see: Org. React., 17, 1 (1969).

/n

For Mannich reaction using tetramethylmethylenediamine as the source of the Mannich intermediate, see: Org. Synth. Coll., 5, 434 (1973).

/n

Reacts with chlorobenzenes to give ferrocenium salts, which can be used to arylate diethyl malonate: Synth. Commun., 18, 291 (1988); J. Chem. Soc., Perkin 1, 469 (1989).

/n

Promotes the Pschorr cyclization of stilbene derivatives in acetone to give phenanthrenes: J. Org. Chem., 60, 196 (1995).

/n

In combination with TFA anhydride, reduces sulfoxides to sulfides at room temperature: Chem. Lett., 400 (2000).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H302

Flammable solid. Harmful if swallowed.

Precautionary Statements: P210-P280a-P240-P241-P301+P312a-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,4037
Hazard Class
4.1
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
LK0700000

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