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17302-46-4 - Methyl 2-hydroxy-5-nitrobenzoate, 98% - 2-Hydroxy-5-nitrobenzoic acid methyl ester - Methyl 5-nitrosalicylate - B25278 - Alfa Aesar

B25278 Methyl 2-hydroxy-5-nitrobenzoate, 98%

CAS Number
17302-46-4
Synonyms
2-Hydroxy-5-nitrobenzoic acid methyl ester
Methyl 5-nitrosalicylate

Size Price ($) Quantity Availability
10g 42.54
50g 143.17
250g 408.80
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Methyl 2-hydroxy-5-nitrobenzoate, 98%

MDL
MFCD00024695
EINECS
241-330-7

Chemical Properties

Formula
C8H7NO5
Formula Weight
197.15
Melting point
114-117°
Solubility
Insoluble in water.

Applications

Methyl 2-hydroxy-5-nitrobenzoate is used as pharmaceutical intermediate.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

John McGinley; Vickie McKee; Hans Toftlund; John M.D.Walsh. Unusual metal coordination chemistry from an amino-amide derivative of 4-nitrophenol, a surprising ligand. Dalton Trans. 2009, (39), 8406-8412.

 

David R.Edwards; Alexei A.Neverov; R.Stan Brown. Dissociative solvolytic cleavage of methyl (ortho-carboxymethyl)aryl phosphate diesters mediated by Yb3+ in methanol gives a 1012-fold rate acceleration attributable to leaving group assistance. J. Am. Chem. Soc. 2009, 131,(1), 368-377.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2918.29
TSCA
No

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