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1603-79-8 - Ethyl phenylglyoxylate, 98% - Ethyl benzoylformate - Phenylglyoxylic acid ethyl ester - B25292 - Alfa Aesar

B25292 Ethyl phenylglyoxylate, 98%

CAS Number
1603-79-8
Synonyms
Ethyl benzoylformate
Phenylglyoxylic acid ethyl ester

Size Price ($) Quantity Availability
5g 22.56
25g 59.53
100g 217.33
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Ethyl phenylglyoxylate, 98%

MDL
MFCD00009120
EINECS
216-504-0

Chemical Properties

Formula
C10H10O3
Formula Weight
178.19
Boiling Point
138-139°/18mm
Flash Point
>110°(230°F)
Density
1.122
Refractive Index
1.5160
Sensitivity
Moisture Sensitive
Solubility
Soluble in water 1143 mg/L @ 25°C .

Applications

Ethyl phenylglyoxylate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible material is strong oxidizing agents.

Literature References

Kiyoshi Tanaka; Tomoya Okada; Fumio Yoneda; Tomohisa Nagamatsu; Kazunori Kuroda. Preparation of chiral 5-deazaflavin derivatives and their asymmetric reduction of ethyl benzoylformate. Tetrahedron Letters. 1984, 25 (16), 1741-1742.

Mária Sutyinszki; Kornél Szöri; Károly Felföldi; Mihály Bartók. 98% Enantioselectivity in the asymmetric synthesis of a useful chiral building block by heterogeneous method: Enantioselective hydrogenation of ethyl-benzoylformate over cinchona modified Pt/Al2O3 catalysts in the acetic acid. Catalysis Communications. 2002, 3 (3), 125-127.

Other References

Harmonized Tariff Code
2918.30
TSCA
Yes

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