Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
Johnson, M. R.; Gauuan, J. F.; Guo, C.; Guzzo, P. R.; Le, V. D.; Shenoy, R. A.; Hamby, J.; Roark, H.; Stier, M.; Mangette, J. E. Synthesis and Characterization of Novel Bi-and Tricyclic α-Amino Acids. Synth. Commun. 2011, 41 (18), 2769-2793.
Tian, G. Q.; Yang, J.; Rosa-Perez, K. γ-Oxygenation of α, β-Unsaturated Esters by Vinylogous O-Nitroso Mukaiyama Aldol Reaction. Org. Lett. 2010, 12 (21), 5072-5074.
Hazard Statements: H227
Precautionary Statements: P210u-P280a-P370+P378a-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.