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18448-47-0 - Methyl 1-cyclohexene-1-carboxylate, 97% - 1-Cyclohexene-1-carboxylic acid methyl ester - B25568 - Alfa Aesar

B25568 Methyl 1-cyclohexene-1-carboxylate, 97%

CAS Number
18448-47-0
Synonyms
1-Cyclohexene-1-carboxylic acid methyl ester

Size Price ($) Quantity Availability
5g 113.30
25g 344.33
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Methyl 1-cyclohexene-1-carboxylate, 97%

MDL
MFCD00001544
EINECS
242-331-5

Chemical Properties

Formula
C8H12O2
Formula Weight
140.18
Boiling Point
190-192°
Flash Point
73°(165°F)
Density
1.030
Refractive Index
1.4770
Solubility
Immiscible with water.

Applications

Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.

Notes

Incompatible with strong oxidizing agents and bases. 

Literature References

Johnson, M. R.; Gauuan, J. F.; Guo, C.; Guzzo, P. R.; Le, V. D.; Shenoy, R. A.; Hamby, J.; Roark, H.; Stier, M.; Mangette, J. E. Synthesis and Characterization of Novel Bi-and Tricyclic α-Amino Acids. Synth. Commun. 2011, 41 (18), 2769-2793.

Tian, G. Q.; Yang, J.; Rosa-Perez, K. γ-Oxygenation of α, β-Unsaturated Esters by Vinylogous O-Nitroso Mukaiyama Aldol Reaction. Org. Lett. 2010, 12 (21), 5072-5074.

GHS Hazard and Precautionary Statements

Hazard Statements: H227

Combustible liquid.

Precautionary Statements: P210-P280-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2916.20
TSCA
No

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