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6-Bromo-1,4-benzodioxane is used as a pharmaceutical intermediate.
Séverine Jeulin; Sébastien Duprat de Paule; Virginie Ratovelomanana-Vidal; Jean-Pierre Genêt; Nicolas Champion and Philippe Dellis.Chiral biphenyl diphosphines for asymmetric catalysis: Stereoelectronic design and industrial perspectives. PNAS. 2004, 101 (16), 5799-5804.
Dr. Lei Liang; Wei Wang; Jun Wu; Fengrong Xu; Dr. Yan Niu; Dr. Bo Xu; Dr. Ping Xu. Rational Design, Green Synthesis, and Initial Evaluation of a Series of Full-Color Tunable Fluorescent Dyes Enabled by the Copper-Catalyzed N-Arylation of 6-Phenyl Pyridazinones and Their Application in Cell Imaging. Chemistry A European Journal. 2013, 19 (41), 13774-13782.
Lithiation can be effected at the 3-position using LDA or LTMP at -78oC: J. Org. Chem., 64, 8004 (1999).