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52287-51-1 - 6-Bromo-1,4-benzodioxane, 98% - 4-Bromo-1,2-(ethylenedioxy)benzene - 3,4-(Ethylenedioxy)bromobenzene - B25625 - Alfa Aesar

B25625 6-Bromo-1,4-benzodioxane, 98%

CAS Number
52287-51-1
Synonyms
4-Bromo-1,2-(ethylenedioxy)benzene
3,4-(Ethylenedioxy)bromobenzene

Size Price ($) Quantity Availability
1g 19.82
5g 61.65
25g 182.70
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6-Bromo-1,4-benzodioxane, 98%

MDL
MFCD00040750
EINECS
257-817-2

Chemical Properties

Formula
C8H7BrO2
Formula Weight
215.05
Boiling Point
259-260°
Flash Point
>110°(230°F)
Density
1.598
Refractive Index
1.5890

Applications

6-Bromo-1,4-benzodioxane is used as a pharmaceutical intermediate.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

Séverine Jeulin; Sébastien Duprat de Paule; Virginie Ratovelomanana-Vidal; Jean-Pierre Genêt; Nicolas Champion and Philippe Dellis.Chiral biphenyl diphosphines for asymmetric catalysis: Stereoelectronic design and industrial perspectives. PNAS. 2004, 101 (16), 5799-5804.

Dr. Lei Liang; Wei Wang; Jun Wu; Fengrong Xu; Dr. Yan Niu; Dr. Bo Xu; Dr. Ping Xu. Rational Design, Green Synthesis, and Initial Evaluation of a Series of Full-Color Tunable Fluorescent Dyes Enabled by the Copper-Catalyzed N-Arylation of 6-Phenyl Pyridazinones and Their Application in Cell Imaging. Chemistry A European Journal. 2013, 19 (41), 13774-13782.

Lithiation can be effected at the 3-position using LDA or LTMP at -78oC: J. Org. Chem., 64, 8004 (1999).

Other References

Beilstein
6223
Harmonized Tariff Code
2932.99
TSCA
No

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