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B25703 1-Aminopyridinium iodide, 97%

CAS Number
6295-87-0
Synonyms

Stock No. Size Price ($) Quantity Availability
B25703-06 5g 37.50
B25703-14 25g 165.00
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1-Aminopyridinium iodide, 97%

MDL
MFCD00051893
EINECS
228-566-6

Chemical Properties

Formula
C5H7IN2
Formula Weight
222.03
Melting point
ca 160° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (almost transparency).

Applications

1-Aminopyridinium iodide is a reagent used as a building block to construct fused heterocycles, synthesis of substituted pyridines, dipolar cycloadditions, ylide type reactions.

Notes

Store in cool, dry place in a well sealed container. Store away from oxidizing agents.

Literature References

D.D. Iarikov; P. Hacarlioglu; S.T. Oyama. Supported room temperature ionic liquid membranes for CO2/CH4 separation. Chemical Engineering Journal. 2011, 166 (1), 401-406.

Virgil Boekelheide; N. A. Fedoruk.Syntheses of fused aromatic heterocycles by 1,3-dipolar addition reactions. 3-Azapyrrocolines. J. Org. Chem. 1968, 33 (5), 2062-2064.

Treatment with base yields a 1,3-dipole (azomethine imine), which undergoes 1,3-cycloaddition with dipolarophiles such as methyl propiolate or acetylenedicarboxylic esters: Tetrahedron Lett., 387 (1962); Org. Process Res. Dev., 2, 320 (1998):

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3713241
Harmonized Tariff Code
2933.39
TSCA
No

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