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55563-79-6 - (S)-(+)-4-Penten-2-ol, 97% - B25728 - Alfa Aesar

B25728 (S)-(+)-4-Penten-2-ol, 97%

CAS Number
55563-79-6
Synonyms

Size Price ($) Quantity Availability
1g 135.00
5g 430.00
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(S)-(+)-4-Penten-2-ol, 97%

MDL
MFCD03427200

Chemical Properties

Formula
C5H10O
Formula Weight
86.13
Boiling Point
115-116°
Flash Point
30°(86°F)
Density
0.837
Refractive Index
1.4250

Applications

(S)-(+)-4-Penten-2-ol is involved in the synthesis of goniothalamin, hexadecanolide, massoia lactone, and parasorbic acid through sequential allylboration-esterification ring-closing metathesis reactions. It is also used to prepare 2-pentanone.

Notes

Incompatible with strong oxidizing agents.

Literature References

Zhang, Y.; Dlugosch, M.; Jübermann, M.; Banwell, M. G.; Ward, J. S. Total Syntheses of the Resorcylic Acid Lactone Neocosmosin A and Its Enantiomer. J. Org. Chem. 2015, 80 (9), 4828-4833.

Warner, M. C.; Bäckvall, J. E. Racemization of Olefinic Alcohols by a Carbonyl(cyclopentadienyl)ruthenium Complex: Inhibition by the Carbon-Carbon Double Bond. Eur. J. Org. Chem. 2015, 2015 (11), 2388-2393.

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P243-P303+P361+P353-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. Take precautionary measures against static discharge. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.29
TSCA
No

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