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H25797 Acetoxyacetyl chloride, 97%

CAS Number
13831-31-7
Synonyms

Stock No. Size Price ($) Quantity Availability
H25797-06 5g 37.50
H25797-14 25g 86.30
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Acetoxyacetyl chloride, 97%

MDL
MFCD00011535
EINECS
237-542-4

Chemical Properties

Formula
C4H5ClO3
Formula Weight
136.53
Boiling Point
55°/12mm
Flash Point
71°(160°F)
Density
1.270
Refractive Index
1.4271
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Reacts with water violently.

Applications

Acetoxyacetyl chloride was used in synthesis of stabilized axial and equatorial conformers of spiro-β-lactams and glycolylhydroxamic acids.

Notes

Moisture sensitive. Store away from oxidizing agents, bases, water/ moisture.

Literature References

Hiromune Ando;, Yusuke Koike; Hideharu Ishida; Makoto Kiso. Extending the possibility of an N-Troc-protected sialic acid donor toward variant sialo-glycoside synthesis. Tetrahedron Letters. 2003, 44 (36), 6883-6886.

OM Walsh; MJ Meegan; RM Prendergast; T Al Nakib. Synthesis of 3-acetoxyazetidin-2-ones and 3-hydroxyazetidin-2-ones with antifungal and antibacterial activity. European Journal of Medicinal Chemistry. 1996, 31 (12), 989-1000.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H314

Combustible liquid. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2918.99
TSCA
No

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