Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

142421-57-6 - Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals - Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine - H25883 - Alfa Aesar

H25883 Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals

CAS Number
142421-57-6
Synonyms
Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine

Size Price ($) Quantity Availability
1g 81.60
5g 241.00
Add to Cart Add to Quote Request View Item

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals

MDL
MFCD01630852
EINECS
000-000-0

Chemical Properties

Formula
C16H6ClF12P
Formula Weight
492.63
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

Notes

Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

Literature References

Hong Jin; Da-yu Wang; Yi-fang Mei; Wen-bing Qiu; Yi Zhou; Dong-ming Wang; Xue-rui Tan; Yu-guang Li. Mitogen-activated protein kinases pathway is involved in physiological testosterone-induced tissue factor pathway inhibitor expression in endothelial cells. Blood Coagulation and Fibrinolysis. 2010, 21 (5), 420-424.

R. Oost; J. Rong; A. J. Minnaard and S. R. Harutyunyan. Synthesis of new derivatives of copper complexes of Josiphos family ligands for applications in asymmetric catalysis. Catal. Sci. Technol. 2014, 4 (7), 1997-2005.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • A10199

    L-Proline, 99%
  • H25885

    Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware