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H25885 Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%

CAS Number
74289-57-9
Synonyms
Bis(3,5-dimethylphenyl)chlorophosphine
Chlorodi(3,5-xylyl)phosphine

Stock No. Size Price ($) Quantity Availability
H25885-03 1g 89.20
H25885-06 5g 322.00
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Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%

MDL
MFCD01630841
EINECS
000-000-0

Chemical Properties

Formula
C16H18ClP
Formula Weight
276.75
Storage & Sensitivity
Moisture Sensitive. May form a Precipitate. Air Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2?-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5?,6,6?,7,7?,8,8?-octahydro-1,1?-binaphthyl (Xyl-H 8 -BINAPO).

Notes

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

Literature References

Rongwei Guo,; Terry T.-L. Au-Yeung,; Jing Wu,; Michael C.K. Choi,;, Albert S.C. Chan. Modified BINAPO ligands for Rh-catalysed enantioselective hydrogenation of acetamidoacrylic acids and esters. Tetrahedron: Asymmetry. 2002, 13 (23), 2519-2522.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

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  • H25888

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