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13685-30-8 - Chlorobis(4-methoxyphenyl)phosphine, 98+% - Bis(4-methoxyphenyl)chlorophosphine - H25887 - Alfa Aesar

H25887 Chlorobis(4-methoxyphenyl)phosphine, 98+%

CAS Number
13685-30-8
Synonyms
Bis(4-methoxyphenyl)chlorophosphine

Size Price ($) Quantity Availability
1g 97.80
5g 294.00
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Chlorobis(4-methoxyphenyl)phosphine, 98+%

MDL
MFCD04972301

Chemical Properties

Formula
C14H14ClO2P
Formula Weight
280.69
Melting point
61-64°
Boiling Point
140°/1.5mm
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Chlorobis(4-methoxyphenyl)phosphine is used an pharmaceutical intermediate.

Notes

Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

Literature References

Masanobu Yatagai; Takamichi Yamagishi; Mitsuhiko Hida. Asymmetric Hydrogenation of Dehydrodipeptides with Rhodium(I)-Chiral Diphosphinites. Selective (S,S)- and (R,R)-Product Formation by Double Asymmetric Induction. Bulletin of the Chemical Society of Japan. 1984, 57 (3), 823-826.

X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene. Acta Cryst. 2012, 68, 922.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P280-P303+P361+P353-P305+P351+P338-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

  • H25883

    Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals
  • H25885

    Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%
  • H26953

    Chlorobis(4-fluorophenyl)phosphine, 98%

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