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H25889 Chlorodi(p-tolyl)phosphine, 95%

CAS Number
1019-71-2
Synonyms
Di(p-tolyl)chlorophosphine
Chlorobis(4-methylphenyl)phosphine

Stock No. Size Price ($) Quantity Availability
H25889-03 1g 89.80
H25889-06 5g 310.00
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Chlorodi(p-tolyl)phosphine, 95%

MDL
MFCD01630844
EINECS
000-000-0

Chemical Properties

Formula
C14H14ClP
Formula Weight
248.69
Boiling Point
180-184°/10mm
Density
1.159
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Reacts with water.

Applications

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

Notes

Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

Literature References

Chi-Feng Lin; Iwao Ojima. Formal enantioselective total synthesis of schulzeines A-C via Pd-catalyzed intramolecular asymmetric allylic amination. Journal of Organic Chemistry. 2011, 76 (15), 6240-6249.

X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene. Acta Cryst. 2012, 68, 922.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

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  • H25888

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  • H25890

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