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181257-35-2 - Chlorodi(2-furyl)phosphine, 98+% - Di(2-furyl)chlorophosphine - H25892 - Alfa Aesar

H25892 Chlorodi(2-furyl)phosphine, 98+%

CAS Number
181257-35-2
Synonyms
Di(2-furyl)chlorophosphine

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Chlorodi(2-furyl)phosphine, 98+%

MDL
MFCD01630851

Chemical Properties

Formula
C8H6ClO2P
Formula Weight
200.56
Boiling Point
102-104°/14mm
Refractive Index
1.5930
Sensitivity
Air & Moisture Sensitive
Solubility
Reacts with water.

Applications

Chlorodi(2-furyl)phosphine is a reactant in the synthesis 2, 2?-bis (di-2-furylphosphino)-1, 1?-binaphthalene. Chlorodi(2-furyl)phosphine is a reactant that is used in the synthesis of centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands, Ferrocene-based chiral diphosphine, and phosphine containing amino acids. In addition, Chlorodi(2-furyl)phosphine can be used as a reactant for α-Arylation of aldehydes, stereoselective sigmatropic rearrangement of acyclic allylic phosphinites and hydrophosphination of functionalized alkenes

Notes

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

Literature References

Frédéric Lirona,; Paul Knochel.Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites . Chem. Commun., 2004, 2004, 304-305.

Frédéric Lirona,; Paul Knochel. Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites. Chem. Commun., 2004, (3), 304-305.

GHS Hazard and Precautionary Statements

Hazard Statements: H261-H314-H318

In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2932.19
TSCA
No

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