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Chlorodi(2-furyl)phosphine is a reactant in the synthesis 2, 2?-bis (di-2-furylphosphino)-1, 1?-binaphthalene. Chlorodi(2-furyl)phosphine is a reactant that is used in the synthesis of centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands, Ferrocene-based chiral diphosphine, and phosphine containing amino acids. In addition, Chlorodi(2-furyl)phosphine can be used as a reactant for α-Arylation of aldehydes, stereoselective sigmatropic rearrangement of acyclic allylic phosphinites and hydrophosphination of functionalized alkenes
Frédéric Lirona,; Paul Knochel.Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites . Chem. Commun., 2004, 2004, 304-305.
Frédéric Lirona,; Paul Knochel. Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites. Chem. Commun., 2004, (3), 304-305.
Hazard Statements: H261-H314-H318
In contact with water releases flammable gas. Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P223-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.