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1069-08-5 - Dichloro(diethylamino)phosphine, 97% - (Diethylamino)dichlorophosphine - Diethylphosphoramidous dichloride - H25934 - Alfa Aesar

H25934 Dichloro(diethylamino)phosphine, 97%

CAS Number
1069-08-5
Synonyms
(Diethylamino)dichlorophosphine
Diethylphosphoramidous dichloride

Size Price ($) Quantity Availability
5g 49.30
25g 138.00
100g 351.00
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Dichloro(diethylamino)phosphine, 97%

MDL
MFCD00013614

Chemical Properties

Formula
C4H10Cl2NP
Formula Weight
174.01
Boiling Point
179°
Flash Point
83°(181°F)
Density
1.196
Refractive Index
1.497
Sensitivity
Moisture Sensitive
Solubility
Reacts violently in water.

Applications

Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols.

Notes

Moisture sensitive. Store away from oxidizing agents, bases, active metals, water/ moisture.

Literature References

Takeshi Matsumoto and François P. Gabbaï. A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand. Organometallics. 2009, 28 (15), 4252-4253.

Kathrin Junge; Günther Oehme; Axel Monsees; Thomas Riermeier; Uwe Dingerdissen; Matthias Beller. Synthesis of new chiral monodentate aminophosphinites and their use in catalytic asymmetric hydrogenations. Journal of Organometallic Chemistry. 2003, 675 (1-2), 91-96.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H314-H318

Combustible liquid. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210u-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

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