Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

H25934 Dichloro(diethylamino)phosphine, 97%

CAS Number
1069-08-5
Synonyms
(Diethylamino)dichlorophosphine
Diethylphosphoramidous dichloride

Stock No. Size Price ($) Quantity Availability
H25934-06 5g 52.30
H25934-14 25g 148.00
H25934-22 100g 365.00
Add to Cart Bulk/Specialty Print Quote View Item

Dichloro(diethylamino)phosphine, 97%

MDL
MFCD00013614

Chemical Properties

Formula
C4H10Cl2NP
Formula Weight
174.01
Boiling Point
179°
Flash Point
83°(181°F)
Density
1.196
Refractive Index
1.497
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Reacts violently in water.

Applications

Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols.

Notes

Moisture sensitive. Store away from oxidizing agents, bases, active metals, water/ moisture.

Literature References

Takeshi Matsumoto and François P. Gabbaï. A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand. Organometallics. 2009, 28 (15), 4252-4253.

Kathrin Junge; Günther Oehme; Axel Monsees; Thomas Riermeier; Uwe Dingerdissen; Matthias Beller. Synthesis of new chiral monodentate aminophosphinites and their use in catalytic asymmetric hydrogenations. Journal of Organometallic Chemistry. 2003, 675 (1-2), 91-96.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H314

Combustible liquid. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

  • A10371

    Ethyl 4-bromocrotonate, tech. 80%
  • A10677

    Phenylglyoxal monohydrate, 97%
  • A11100

    1,4-Cyclohexanedione, 98%
  • A16901

    N,N'-Dimethyl-1,3-propanediamine, 97%
  • B20347

    (Trifluoromethyl)trimethylsilane, 98%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware