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H25937 2-Methoxyethyl chloroformate, tech. 85%

CAS Number
628-12-6
Synonyms
Chloroformic acid 2-methoxyethyl ester

Stock No. Size Price ($) Quantity Availability
H25937-AK 250ml 672.00
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2-Methoxyethyl chloroformate, tech. 85%

MDL
MFCD00058932
EINECS
211-026-9

Chemical Properties

Formula
CH3OCH2CH2CO2Cl
Formula Weight
138.55
Boiling Point
157-158°
Flash Point
59°(138°F)
Density
1.192
Refractive Index
1.4200
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in most organic solvents.

Applications

2-methoxyethyl chloroformate was used to produce di-2-dimethoxyethyl hydrazine carboxylate(alternative reagent for the mitsunobu reaction).

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

S Challenger,; L Dudin,; J DaSilva. Green Chemistry Articles of Interest to the Pharmaceutical Industry. Organic Process Research & Development. 2008, 12 807-816.

Takashi Sugimura,; Kazutake Hagiya. Di-2-methoxyethyl Azodicarboxylate (DMEAD): An Inexpensive and Separation-friendly Alternative Reagent for the Mitsunobu Reaction. Chemistry Letters. 2007, 36 (4), 566-567.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H314-H330-H335

Flammable liquid and vapour. Causes severe skin burns and eye damage. Fatal if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2918.99
TSCA
No

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