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628-12-6 - 2-Methoxyethyl chloroformate, tech. 85% - Chloroformic acid 2-methoxyethyl ester - H25937 - Alfa Aesar

H25937 2-Methoxyethyl chloroformate, tech. 85%

CAS Number
628-12-6
Synonyms
Chloroformic acid 2-methoxyethyl ester

Size Price ($) Quantity Availability
5ml 0.00
25ml 0.00
250ml 576.80
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2-Methoxyethyl chloroformate, tech. 85%

MDL
MFCD00058932
EINECS
211-026-9

Chemical Properties

Formula
CH3OCH2CH2CO2Cl
Formula Weight
138.55
Boiling Point
157-158°
Flash Point
59°(138°F)
Density
1.192
Refractive Index
1.4200
Sensitivity
Moisture Sensitive
Solubility
Soluble in most organic solvents.

Applications

2-methoxyethyl chloroformate was used to produce di-2-dimethoxyethyl hydrazine carboxylate(alternative reagent for the mitsunobu reaction).

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

S Challenger,; L Dudin,; J DaSilva. Green Chemistry Articles of Interest to the Pharmaceutical Industry. Organic Process Research & Development. 2008, 12 807-816.

Takashi Sugimura,; Kazutake Hagiya. Di-2-methoxyethyl Azodicarboxylate (DMEAD): An Inexpensive and Separation-friendly Alternative Reagent for the Mitsunobu Reaction. Chemistry Letters. 2007, 36 (4), 566-567.

GHS Hazard and Precautionary Statements

Hazard Statements: H330-H314-H318-H226

Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour.

Precautionary Statements: P210-P260-P284-P303+P361+P353-P304+P340-P305+P351+P338-P320-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2918.99
TSCA
No

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