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88335-93-7 - (1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98% - (1S,2R)-1-Methyl cis-1,2,3,6-tetrahydrophthalate - (1S,2R)-1-Methyl cis-4-cyclohexene-1,2-dicarboxylate - H25950 - Alfa Aesar

H25950 (1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%

CAS Number
88335-93-7
Synonyms
(1S,2R)-1-Methyl cis-1,2,3,6-tetrahydrophthalate
(1S,2R)-1-Methyl cis-4-cyclohexene-1,2-dicarboxylate

Size Price ($) Quantity Availability
1g 95.40
5g 336.00
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(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester, 98%

MDL
MFCD00075490
EINECS
000-000-0

Chemical Properties

Formula
C9H12O4
Formula Weight
184.19
Melting point
64-67°
Solubility
Insoluble in water.

Applications

(1S,2R)-cis-4-Cyclohexene-1,2-dicarboxylic acid 1-monomethyl ester is used in organic synthesis as a starting material and intermediate.

Notes

Incompatible with strong oxidizing agents, strong acid and bases.

Literature References

Goswami, A.; Kissick, T. P. Enzymatic Desymmetrization of Dimethyl Cylcohex-4-ene-cis-1,2-dicarboxylate to (1S,2R)-2-(Methoxycarbonyl)cyclohex-4-ene-1-carboxylic Acid. Org. Process Res. Dev. 2009, 13 (3), 483-488.

Solano, D. M.; Hoyos, P.; Hernáiz, M. J.; Alcántara, A. R.; Sánchez-Montero, J. M. Industrial biotransformations in the synthesis of building blocks leading to enantiopure drugs. Bioresour. Technol. 2012, 115, 196-207.

Su?ss, P.; Illner, S.; von Langermann, J.; Borchert, S.; Bornscheuer, U. T.; Wardenga, R.; Kragl, U. Scale-Up of a Recombinant Pig Liver Esterase-Catalyzed Desymmetrization of Dimethyl Cyclohex-4-ene-cis-1,2-dicarboxylate. Org. Process Res. Dev. 2014, 18 (7), 897-903.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
5262096
Harmonized Tariff Code
2917.20
TSCA
No

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