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H26014 tert-Butyl N-allylcarbamate, 97%

CAS Number
78888-18-3
Synonyms
N-Allylcarbamic acid tert-butyl ester

Stock No. Size Price ($) Quantity Availability
H26014-09 10g 56.40
H26014-18 50g 171.00
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tert-Butyl N-allylcarbamate, 97%

MDL
MFCD00191870

Chemical Properties

Formula
C8H15NO2
Formula Weight
157.21
Melting point
34-39°
Boiling Point
48-50°/1mm
Flash Point
79°(175°F)
Density
0.938
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water. Soluble in methanol.

Applications

tert-Butyl N-allylcarbamate is used in the synthesis of isoxazolidines. Synthesis of 5-substituted thiazolidin-2-ones is from the reaction of xanthates and tert-butyl N-allylcarbamates .

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Antonio Rescifinaa; Ugo Chiacchioa; Antonino Corsaroa; Anna Pipernob; Roberto Romeob. Isoxazolidinyl polycyclic aromatic hydrocarbons as DNA-intercalating antitumor agents. European Journal of Medicinal Chemistry. 2011, 46 (1) ,129-136.

Zhongyan Huang,; Jiaxi Xu. Efficient synthesis of 5-substituted thiazolidin-2-ones from xanthates and tert-butyl N-allylcarbamates . Tetrahedron. 2013, 69 (48), 10272-10278.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2924.19
TSCA
No

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