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4,4-Difluorocyclohexanone is used as a pharmaceutical intermediate.
Ruth E. Lack; Camille Ganter; John D. Roberts. Nuclear magnetic resonance spectroscopy. Conformational equilibria and equilibration of 4,4-difluorocyclohexanone and 6,6-difluoro-cis-decal-2-ones. J. Am. Chem. Soc. 1968, 90 (25), 7001-7007.
William R. Dolbier; Jorge H. Alonso. Secondary deuterium isotope effects in pericyclic reactions. Thermal rearrangement of dideuteriobiscyclopropylidene. J. Am. Chem. Soc. 1973, 95 (13), 4421-4423.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant